Potential Replacement of Pentaeritritol Tetranitrate Explosive Aggregate Polymer (Petn): A Short Review

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Explanation of the colossal detonation sensitivity of silicon pentaerythritol tetranitrate (Si-PETN) explosive.

DFT calculations have identified the novel rearrangement shown here for decomposition of the Si derivative of the PETN explosive [PentaErythritol TetraNitrate (PETN), C(CH(2)ONO(2))(4)] that explains the very dramatic increase in sensitivity observed experimentally. The critical difference is that Si-PETN allows a favorable five-coordinate transition state in which the new Si-O and C-O bonds fo...

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Pentaerythritol tetranitrate (PETN) is a common secondary explosive and has been used extensively to study shock initiation and energy propagation in energetic materials. We report 2D IR measurements of PETN thin films that resolve vibrational energy transfer and relaxation mechanisms. Ultrafast anisotropy measurements reveal a sub-500 fs reorientation of transition dipoles in thin films of vap...

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Modeling deflagration-to-detonation transition in granular explosive pentaerythritol tetranitrate

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ژورنال

عنوان ژورنال: Archives in Biomedical Engineering & Biotechnology

سال: 2019

ISSN: 2687-8100

DOI: 10.33552/abeb.2019.02.000549